Dr. Frank Hauke

Dr. Frank Hauke


Academic High Council


Zentralinstitut für Neue Materialien und Prozesstechnik Zentralinstitut für Neue Materialien und Prozesstechnik


Room: 219
Phone: +49 (0) 911 650 78 650 01
Fax: +49 (0) 911 65078 650 15


Diploma Thesis

Mannich Funktionalisierung von C59N

Ph.D. Thesis

Chemische Funktionalisierung des Heterofulleren-Dimers (C59N)2


81)J. Gebhardt, S. Bosch, F. Hof, F. Hauke, A. Hirsch, A. Görling
Selective reduction of SWCNTs – concepts and insights
J. Mater. Chem. C 2016,
80)G. Abellán, V. Lloret, U. Mundloch, M. Marcia, C. Neiss, A. Görling, M. Varela, F. Hauke, A. Hirsch
Noncovalent Functionalization of Black Phosphorus
Angew. Chem. Int. Ed. 2016, 55, 14557-14562
79)R. A. Schäfer, K. Weber, M. Kolesnik-Gray, F. Hauke, V. Kristic, B. Meyer, A. Hirsch
Substrate-Modulated Reductive Graphene Functionalization
J. Am. Chem. Soc. 2016, 138, 1647-1652
78)M. Marcia, C. Vinh, C. Dolle, G. Abellán, J. Schönamsgruber, T. Schunk, B. Butz, E. Spiecker, F. Hauke, A. Hirsch
Highly Integrated Organic–Inorganic Hybrid Architectures by Noncovalent Exfoliation of Graphite and Assembly with Zinc Oxide Nanoparticles
Adv. Mater. Interfaces 2016, 3, 1600365
77)K. C. Knirsch, F. Hof, V. Lloret, U. Mundloch, F. Hauke, A. Hirsch
Topology-Driven Reductive Silylation of Synthetic Carbon Allotropes
J. Am. Chem. Soc. 2016, 138, 15642-15647
76)J. A. Carrasco, J. Romero, M. Varela, F. Hauke, G. Abellán, A. Hirsch, E. Coronado Alkoxide-intercalated NiFe-layered double hydroxides magnetic nanosheets as efficient water oxidation electrocatalystsInorg. Chem. Front. 2016, 3, 478-487
75)C. Gibaja, D. Rodriguez-San-Miguel, P. Ares, J. Gómez-Herrero, M. Varela, R. Gillen, J. Maultzsch, F. Hauke, A. Hirsch, G. Abellán, F. Zamora Few-Layer Antimonene by Liquid-Phase ExfoliationAng. Chem. Int. Ed. 2016, 55, 14345-14349
74)R. A. Schäfer, D. Dasler, U. Mundloch, F. Hauke, A. Hirsch Basic Insights into Tunable Graphene HydrogenationJ. Am. Chem. Soc. 2016, 138, 1647-1652
73)K. C. Knirsch, R. A. Schäfer, F. Hauke, A. Hirsch Mono- and Ditopic Bisfunctionalization of GrapheneAngew. Chem. Int. Ed. 2016, 55, 5861-5864
72)P. Vecera, J. Holzwarth, K. F. Edelthalhammer, U. Mundloch, H. Peterlik, F. Hauke, A. Hirsch Solvent-driven electron trapping and mass transport in reduced graphites to access perfect grapheneNat. Commun. 2016, 7, 12411
71)K. C. Knirsch, N. C. Berner, H. C. Nerl, C. S. Cucinotta, Z. Gholamvand, N. McEvoy, Z. Wang, I. Abramovic, P. Vecera, M. Halik, S. Sanvito, G. S. Duesberg, V. Nicolosi, F. Hauke, A. Hirsch, J. N. Coleman, C. Backes Basal-Plane Functionalization of Chemically Exfoliated Molybdenum Disulfide by Diazonium SaltsACS Nano 2015, 9, 6018-6030
70)D. Hanlon, C. Backes, E. Doherty, C. S. Cucinotta, N. C. Berner, C. Boland, K. Lee, A. Harvey, P. Lynch, Z. Gholamvand, S. Zhang, K. Wang, G. Moynihan, A. Pokle, Q. M. Ramasse, N. McEvoy, W. J. Blau, J. Wang, G. Abellan, F. Hauke, A. Hirsch, S. Sanvito, D. D. O'Regan, G. S. Duesberg, V. Nicolosi, J. N. Coleman Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronicsNat. Commun. 2015, 6, 8563
69)V. Strauss, R. A. Schäfer, F. Hauke, A. Hirsch, D. M. Guldi Polyhydrogenated Graphene: Excited State Dynamics in Photo- and Electroactive Two-Dimensional DomainsJ. Am. Chem. Soc. 2015, 137, 13079-13086
68)B. G. Márkus, F. Simon, J. C. Chacón-Torres, S. Reich, P. Szirmai, B. Náfrádi, L. Forró, T. Pichler, P. Vecera, F. Hauke, A. Hirsch Transport, magnetic and vibrational properties of chemically exfoliated few-layer graphenePhys. Status Solidi B 2015, n/a-n/a
67)S. Bosch, L. Zeininger, F. Hauke, A. Hirsch A supramolecular approach for the facile solubilization and separation of covalently functionalized single-walled carbon nanotubesChemistry - A European Journal 2014, 20, 2537-2541
66)F. Hof, F. Hauke, A. Hirsch Brominated single walled carbon nanotubes as versatile precursors for covalent sidewall functionalizationChemical Communications 2014, 50, 6582-6584
65)F. Hof, R. A. Schäfer, C. Weiss, F. Hauke, A. Hirsch Novel λ3-Iodane-Based Functionalization of Synthetic Carbon Allotropes (SCA)-Common Concepts and Quantification of the Degree of AdditionChemistry - A European Journal 2014, 20, 16644-16651
64)M. Marcia, P. Singh, F. Hauke, M. Maggini, A. Hirsch Novel EDTA-ligands containing an integral perylene bisimide (PBI) core as an optical reporter unitOrganic and Biomolecular Chemistry 2014, 12, 7045-7058
63)P. Vecera, K. Edelthalhammer, F. Hauke, A. Hirsch Reductive arylation of graphene: Insights into a reversible carbon allotrope functionalization reactionPhys. Status Solidi B 2014, 251, 2536-2540
62)F. Jakubka, C. Backes, F. Gannott, U. Mundloch, F. Hauke, A. Hirsch, J. Zaumseil Mapping Charge Transport by Electroluminescence in Chirality-Selected Carbon Nanotube NetworksACS Nano 2013, 7, 7428-7435
61)F. Hof, S. Bosch, S. Eigler, F. Hauke, A. Hirsch New Basic Insight into Reductive Functionalization Sequences of Single Walled Carbon Nanotubes (SWCNTs)Journal of the American Chemical Society 2013, 135, 18385-18395
60)R. A. Schäfer, J. M. Englert, P. Wehrfritz, W. Bauer, F. Hauke, T. Seyller, A. Hirsch On the way to graphane-pronounced fluorescence of polyhydrogenated grapheneAngewandte Chemie International Edition 2013, 52, 754-7
59)J. Laudenbach, B. Gebhardt, Z. Syrgiannis, F. Hauke, A. Hirsch, J. Maultzsch Raman bands of nano-graphene flakes on carbon nanotubes after oxidationphysica status solidi (b) 2013, 250, 2687-2691
58)Z. Wang, S. Mohammadzadeh, T. Schmaltz, J. Kirschner, A. Khassanov, S. Eigler, U. Mundloch, C. Backes, H. Steinrück, A. Magerl, F. Hauke, A. Hirsch, M. Halik Region-Selective Self-Assembly of Functionalized Carbon Allotropes from SolutionACS Nano 2013, 7, 11427-11434
57)J. M. Englert, P. Vecera, K. C. Knirsch, R. A. Schäfer, F. Hauke, A. Hirsch Scanning-Raman-Microscopy for the Statistical Analysis of Covalently Functionalized GrapheneACS nano 2013, 7, 5472
56)K. C. Knirsch, J. M. Englert, C. Dotzer, F. Hauke, A. Hirsch Screening of the chemical reactivity of three different graphite sources using the formation of reductively alkylated graphene as a model reactionChemical Communications 2013, 49, 10811-10813
55)C. Backes, F. Hauke, A. Hirsch Tuning the adsorption of perylene-based surfactants on the surface of single-walled carbon nanotubesphysica status solidi (b) 2013, 250, 2592-2598
54)A. Hirsch, J. M. Englert, F. Hauke Wet chemical functionalization of grapheneAccounts of chemical research 2013, 46, 87-96
53)F. Jakubka, S. P. Schießl, S. Martin, J. M. Englert, F. Hauke, A. Hirsch, J. Zaumseil Effect of Polymer Molecular Weight and Solution Parameters on Selective Dispersion of Single-Walled Carbon NanotubesACS Macro Letters 2012, 1, 815-819
52)J. M. Englert, K. C. Knirsch, C. Dotzer, B. Butz, F. Hauke, E. Spiecker, A. Hirsch Functionalization of graphene by electrophilic alkylation of reduced graphiteChemical Communications 2012, 48, 5025
51)F. Hof, S. Bosch, J. M. Englert, F. Hauke, A. Hirsch Statistical Raman Spectroscopy: An Method for the Characterization of Covalently Functionalized Single-Walled Carbon NanotubesAngewandte Chemie International Edition 2012, 51, 11727
50)B. Gebhardt, Z. Syrgiannis, C. Backes, R. Graupner, F. Hauke, A. Hirsch Carbon Nanotube Sidewall Functionalization with Carbonyl Compounds—Modified Birch Conditions vs the Organometallic Reduction ApproachJournal of the American Chemical Society 2011, 133, 7985-7995
49)C. Backes, T. Schunk, F. Hauke, A. Hirsch Counterion effect on the aggregation of anionic perylene dyes and the influence on carbon nanotube dispersion efficienciesJ. Mater. Chem. 2011, 21, 3554-3557
48)J. M. Englert, C. Dotzer, G. Yang, M. Schmid, C. Papp, M. J. Gottfried, H. Steinrück, E. Spiecker, F. Hauke, A. Hirsch Covalent bulk functionalization of grapheneNature Chemistry 2011, 3, 279-286
47)C. Backes, S. Bosch, U. Mundloch, F. Hauke, A. Hirsch Density Gradient Ultracentrifugation on Carbon Nanotubes According to Structural Integrity as a Foundation for an Absolute Purity EvaluationChemPhysChem 2011, 12, 2576-2580
46)C. Oelsner, C. Schmidt, F. Hauke, M. Prato, A. Hirsch, D. M. Guldi Interfacing Strong Electron Acceptors with Single Wall Carbon NanotubesJournal of the American Chemical Society 2011, 133, 4580-4586
45)C. Backes, C. D. Schmidt, F. Hauke, A. Hirsch Perylene-Based Nanotweezers: Enrichment of Larger-Diameter Single-Walled Carbon NanotubesChemistry - An Asian Journal 2011, 6, 438-444
44)B. Gebhardt, F. Hof, C. Backes, M. Müller, T. Plocke, J. Maultzsch, C. Thomsen, F. Hauke, A. Hirsch Selective polycarboxylation of semiconducting single-walled carbon nanotubes by reductive sidewall functionalizationJournal of the American Chemical Society 2011, 133, 19459-19473
43)C. Backes, F. Hauke, A. Hirsch The Potential of Perylene Bisimide Derivatives for the Solubilization of Carbon Nanotubes and GrapheneAdvanced Materials 2011, 23, 2588-2601
42)B. Gebhardt, R. Graupner, F. Hauke, A. Hirsch A Novel Diameter-Selective Functionalization of SWCNTs with Lithium AlkynylidesEuropean Journal of Organic Chemistry 2010, 1494-1501
41)E. Karabudak, C. Backes, F. Hauke, C. D. Schmidt, H. Cölfen, A. Hirsch, W. Wohlleben A Universal Ultracentrifuge Spectrometer Visualizes CNT-Intercalant-Surfactant ComplexesChemPhysChem 2010, 11, 3224-3227
40) F. Hauke, A. Hirsch Covalent Functionalization of Carbon Nanotubesin: Carbon Nanotubes and Related Structures: Synthesis, Characterization, Functionalization, and Applications; D. M. Guldi, N. Martín (Eds.)
Wiley-VCH Verlag, Weinheim, Germany, 2010, 135-198
39)C. Backes, E. Karabudak , C. D. Schmidt, F. Hauke, A. Hirsch, W. Wohlleben Determination of the Surfactant Density on SWCNTs by Analytical UltracentrifugationChemistry - A European Journal 2010, 16, 13176-13184
38)C. Backes, U. Mundloch, A. Ebel, F. Hauke, A. Hirsch Dispersion of HiPco® and CoMoCAT® Single-Walled Nanotubes (SWNTs) by Water Soluble Pyrene Derivatives-Depletion of Small Diameter SWNTsChemistry - A European Journal 2010, 16, 3314-3317
37)M. Müller, R. Meinke, J. Maultzsch, Z. Syrgiannis, F. Hauke, Á. Pekker, K. Kamarás, A. Hirsch, C. Thomsen Electronic Properties of Propylamine-Functionalized Single-Walled Carbon NanotubesChemPhysChem 2010, 11, 2444-2448
36)C. Backes, U. Mundloch, C. D. Schmidt, J. N. Coleman, W. Wohlleben, F. Hauke, A. Hirsch Enhanced Adsorption Affinity of Anionic Perylene-Based Surfactants towards Smaller-Diameter SWCNTsChemistry - A European Journal 2010, 16, 13185-13192
35)J. M. Englert, F. Hauke, X. Feng, K. Müllen, A. Hirsch Exfoliation of hexa-peri-hexabenzocoronene in waterChemical Communications 2010, 46, 9194
34)C. Backes, C. D. Schmidt, K. Rosenlehner, F. Hauke, J. N. Coleman, A. Hirsch Nanotube Surfactant Design: The Versatility of Water-Soluble Perylene BisimidesAdvanced Materials 2010, 22, 788-802
33)N. V. Kozhemyakina, J. M. Englert, G. Yang, E. Spiecker, C. D. Schmidt, F. Hauke, A. Hirsch Non-Covalent Chemistry of Graphene: Electronic Communication with Dendronized Perylene BisimidesAdvanced Materials 2010, 22, 5483-5487
32)C. Backes, J. M. Englert, N. Bernhard, F. Hauke, A. Hirsch Optical Visualization of Carbon Nanotubes-a Unifying Linkage Between Microscopic and Spectroscopic Characterization TechniquesSmall 2010, 6, 1968-1973
31)Z. Syrgiannis, B. Gebhardt, C. Dotzer, F. Hauke, R. Graupner, A. Hirsch Reductive Retrofunctionalization of Single-Walled Carbon NanotubesAngew. Chem., Int. Ed. 2010, 49, 3322-3325
30)Z. Syrgiannis, B. Gebhardt, C. Dotzer, F. Hauke, R. Graupner, A. Hirsch Reduktive Retro-Funktionalisierung einwandiger KohlenstoffnanoröhrenAngewandte Chemie 2010, 122, 3394-3397
29)M. Müller, R. Meinke, J. Maultzsch, B. Gebhardt, F. Hauke, A. Hirsch, C. Thomsen Resonant Raman scattering on carbon nanotubes covalently functionalized with lithium decynephysica status solidi (b) 2010, 247, 2863-2866
28)C. Backes, F. Hauke, C. D. Schmidt, A. Hirsch Fractioning HiPco and CoMoCAT SWCNTs via density gradient ultracentrifugation by the aid of a novel perylene bisimide derivative surfactantChemical Communications 2009, 2643
27)C. Backes, C. D. Schmidt, F. Hauke, C. Böttcher, A. Hirsch High Population of Individualized SWCNTs through the Adsorption of Water-Soluble PerylenesJournal of the American Chemical Society 2009, 131, 2172-2184
26)C. Ehli, C. Oelsner, D. M. Guldi, A. Mateo-Alonso, M. Prato, C. Schmidt, C. Backes, F. Hauke, A. Hirsch Manipulating single-wall carbon nanotubes by chemical doping and charge transfer with perylene dyesNature Chemistry 2009, 1, 243-249
25)J. M. Englert, J. Röhrl, C. D. Schmidt, R. Graupner, M. Hundhausen, F. Hauke, A. Hirsch Soluble Graphene: Generation of Aqueous Graphene Solutions Aided by a Perylenebisimide-Based BolaamphiphileAdvanced Materials 2009, 21, 4265-4269
24)F. Spänig, C. Kovacs, F. Hauke, K. Ohkubo, S. Fukuzumi, D. M. Guldi, A. Hirsch Tuning Charge Transfer Energetics in Reaction Center Mimics via Th -Functionalization of FullerenesJournal of the American Chemical Society 2009, 131, 8180-8195
23)Z. Syrgiannis, F. Hauke, J. Röhrl, M. Hundhausen, R. Graupner, Y. Elemes, A. Hirsch Covalent Sidewall Functionalization of SWNTs by Nucleophilic Addition of Lithium AmidesEuropean Journal of Organic Chemistry 2008, 2544-2550
22)M. von Delius, F. Hauke, A. Hirsch Evaluation of an Intramolecular Approach for the Synthesis of the Elusive C58N2 Heterofullerene FamilyEuropean Journal of Organic Chemistry 2008, 4109-4119
21)D. Wunderlich, F. Hauke, A. Hirsch Preferred functionalization of metallic and small-diameter single walled carbon nanotubes via reductive alkylationJournal of Materials Chemistry 2008, 18, 1493
20)D. Wunderlich, F. Hauke, A. Hirsch Preferred Functionalization of Metallic and Small-Diameter Single-Walled Carbon Nanotubes by Nucleophilic Addition of Organolithium and -Magnesium Compounds Followed by ReoxidationChemistry - A European Journal 2008, 14, 1607-1614
19)F. Hauke, Z. F. Chen, A. Hirsch Complete assignment of all 13C NMR signals of Cs symmetric monoazafullerene derivatives by comparison of experimental and calculated spectraPolish Journal of Chemistry 2007, 81, 971-983
18)F. Simon, D. Quintavalle, A. Jánossy, B. Náfrádi, L. Forró, H. Kuzmany, F. Hauke, A. Hirsch, J. Mende, M. Mehring Metallic bundles of single-wall carbon nanotubes probed by electron spin resonancephysica status solidi (b) 2007, 244, 3885-3889
17)F. Hauke, S. Atalick, D. M. Guldi, A. Hirsch Covalently linked heterofullerene–porphyrin conjugates; new model systems for long-lived intramolecular charge separationTetrahedron 2006, 62, 1923-1927
16)F. Simon, H. Kuzmany, J. Bernardi, F. Hauke, A. Hirsch Encapsulating C59N azafullerene derivatives inside single-wall carbon nanotubesCarbon 2006, 44, 1958-1962
15)F. Simon, H. Kuzmany, F. Fülöp, A. Jánossy, J. Bernardi, F. Hauke, A. Hirsch Encapsulating C59N azafullerenes inside single-wall carbon nanotubesphysica status solidi (b) 2006, 243, 3263-3267
14)F. Simon, H. Kuzmany, B. Náfrádi, T. Fehér, L. Forró, F. Fülöp, A. Jánossy, L. Korecz, A. Rockenbauer, F. Hauke, A. Hirsch Magnetic Fullerenes inside Single-Wall Carbon NanotubesPhysical Review Letters 2006, 97, 136801-136804
13)F. Hauke, O. Vostrowsky, A. Hirsch, A. Quaranta, W. Leibl, S. Leach, R. Edge, S. Navaratnam, R. V. Bensasson Monomeric Azaheterofullerene Derivatives RC59N: Influence of the R Moiety on Spectroscopic and Photophysical PropertiesChemistry - A European Journal 2006, 12, 4813-4820
12)F. Hauke, A. Hirsch, S. Atalick, D. Guldi Quantitative Transduction of Excited-State Energy in Fluorophore-Heterofullerene ConjugatesEuropean Journal of Organic Chemistry 2005, 1741-1751
11)F. Hauke, S. Atalick, D. M. Guldi, J. Mack, L. T. Scott, A. Hirsch Molecular satellite dishes: attaching parabolic and planar arenes to heterofullerenesChemical Communications 2004, 766
10)F. Hauke, M. Ángeles Herranz, L. Echegoyen, D. Guldi, A. Hirsch, S. Atalick The first fullerene–heterofullerene dyadChemical Communications 2004, 600-601
9)K. Kim, F. Hauke, A. Hirsch, P. D. W. Boyd, E. Carter, R. S. Armstrong, P. A. Lay, C. A. Reed Synthesis of the C59N+ Carbocation. A Monomeric Azafullerene Isoelectronic to C60Journal of the American Chemical Society 2003, 125, 4024-4025
8)F. Hauke, A. Hirsch, S. Liu, L. Echegoyen, A. Swartz, C. Luo, D. M. Guldi Evidence of Pronounced Electronic Coupling in a Directly Bonded Fullerene-Ferrocene DyadChemPhysChem 2002, 3, 195-205
7)D. M. Guldi, F. Hauke, A. Hirsch Fullerenes (C60) versus heteroazafullerenes (C59N); a photophysical comparison of their monoadducts and hexaadductsResearch on Chemical Intermediates 2002, 28, 817-830
6)Y. V. Vasil'ev, R. R. Abzalimov, S. K. Nasibullaev, R. F. Tuktarov, F. Hauke, U. Reuther, A. Hirsch, T. Drewello Negative Molecular Ions of Azafullerenes and Their Hydrogenated DerivativesPhys. Sol. State 2002, 44, 554-556
5)F. Hauke, A. Swartz, D. M. Guldi, A. Hirsch Supramolecular assembly of a quasi-linear heterofullerene–porphyrin dyadJournal of Materials Chemistry 2002, 12, 2088-2094
4)F. Hauke, A. Hirsch C59N+: A key intermediate in azaheterofullerene chemistryTetrahedron 2001, 57, 3697-3708
3)F. Hauke, A. Hirsch Regioselective formation of highly functionalised heterofullerenes: pentamalonates of RC59N involving an octahedral addition patternChemical Communications 2001, 1316-1317
2)S. Eisebitt, A. Karl, A. Zimina, R. Scherer, M. Freiwald, W. Eberhardt, F. Hauke, A. Hirsch, Y. Achiba Electronic structure of doped fullerenes and single wall carbon nanotubesAIP Conference Proceedings 2000, 544, 380-384
1)F. Hauke, A. Hirsch Mannich functionalization of C59NChemical Communications 1999, 2199-2200